High-resolution solid-state NMR of silicates and zeolites

  • 485 Pages
  • 4.92 MB
  • 4758 Downloads
  • English
by
Wiley , Chichester [West Sussex], New York
Silicates -- Analysis., Zeolites -- Analysis., Nuclear magnetic resonance spectros
StatementGünter Engelhardt, Dieter Michel.
ContributionsMichel, Dieter.
Classifications
LC ClassificationsQD181.S6 E55 1987
The Physical Object
Paginationxiv, 485 p. :
ID Numbers
Open LibraryOL2379605M
ISBN 100471915971
LC Control Number87008137

Covers the dramatic developments in the past decade in the applications of high-resolution NMR to the study of solid materials such as inorganic silicates, aluminosilicates, and in particular, zeolites. Also covers a variety of NMR methods, including conventional FT NMR techniques, used to investigate sorbate-sorbent interactions and the structure of adsorbed molecules.

Book Review. Book Review: High‐Resolution Soild‐State NMR of Silicates and Zeolites. By G. Engelhardt and D.

Michel. Werner Müller‐Warmuth. Insitut für Physikalische Chemie der Universität Münster (FRG) Search for more papers by this : Werner Müller-Warmuth. The potential of 2D {sup 29}Si high-resolution solid-state NMR spectroscopy to establish three-dimensional Si/O/Si lattice connectivities in zeolites has been investigated using a {sup 29}Si-enriched sample of zeolite ZSM High-resolution solid-state NMR of silicates and zeolites.

Chichester [West Sussex] ; New York: Wiley, © (OCoLC) Document Type: Book: All Authors / Contributors: Günter Engelhardt. An account is given on the wide range of applications of multinuclear high-resolution solid-state NMR spectroscopy in silicate and zeolite science, with special emphasis on the various kinds of chemical information retrievable from the NMR experiments.

Although a concise survey is given on the basic principles and methods of high-resolution solid-state NMR, some familiarity with the general fundamentals of NMR spectroscopy.

English, Book, Illustrated edition: High-resolution solid-state NMR of silicates and zeolites / Günter Engelhardt, Dieter Michel. --Applied Spectroscopy This well-organized and up-to-date text gives a thorough account of the wide range of applications of multinuclear high-resolution solid-state NMR spectroscopy in silicate and zeolite science, with emphasis on the kinds of chemical information retrievable from NMR experiments.

(0 ) s: 3. --Applied Spectroscopy This well-organized and up-to-date text gives a thorough account of the wide range of applications of multinuclear high-resolution solid-state NMR spectroscopy in silicate. Solid state NMR 27 Al MAS NMR 29 Si MAS NMR Pb static NMR MQ-MAS, Inorganic pigments pottery volcanic tuffs zeolites glasses welded tuff lithified tuff chabazite phillipsite This is a preview of subscription content, log in to check access.

Effect of Al/Si Substitutions and Silanol Nests on the Local Geometry of Si and Al Framework Sites in Silicone-Rich Zeolites: A Combined High Resolution 27Al and 29Si NMR and Density Functional Theory/Molecular Mechanics Study.

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The Journal of Physical Chemistry C(32), DOI: /jp   The high resolution 29 Si solid-state NMR spectrum of a pure silica zeolite with the CON framework [ 66] was obtained on a material that initially was a borosilicate zeolite, but was subsequently deboronated by treatment with acetic acid.

About this book. Solid-State NMR Characterization of Heterogeneous Catalysts and Catalytic Reactions provides a comprehensive account of state-of-the-art solid-state NMR techniques and the application of these techniques in heterogeneous catalysts and related catalytic reactions.

Nuclear magnetic resonance (NMR) The first application of high-resolution solid-state NMR with magic-angle-spinning (MAS-NMR) to the investigation of silicates and silicoaluminates was made by Lippmaa et al.

Details High-resolution solid-state NMR of silicates and zeolites FB2

(Ill They showed clearly that distinct the 29Si-NMR spectra of zeolite Y and ZSM are compared. The spectrum of. About For Books High-resolution Solid-state Nuclear Magnetic Resonance of Silicates and Zeolites. fields are essential to obtain "high resolution" 27A1 MAS NMR spectra in the solid state.

STUQIES Of KIGH Si/Al ZEOLITES There are two likely contributing factors to line broadening in 29Si spectra of zeolites: unaveraged dipolar interactions between 29Si and 27Al and distributions of local environments. High-resolution solid state NMR of silicates and zeolites, Wiley, New York ().

Abstract. Since the first systematic study of silicates and aluminosilicates by high-resolution solid-state 29 Si NMR was published in [1], the application of this method has grown rapidly and is fast becoming a powerful tool in the structural characterization of a wide range of silicates and other silicon-containing materials.

The development is closely related to the great progress made. Brand new Book. High-Resolution Solid-State NMR of Silicates and Zeolites Gunter Engelhardt and Dieter Michel "I strongly recommend this book as an important reference for scientists concerned with the structural properties of siliceous materials.".

• G. Engelhardt, D. Michel: "High Resolution Solid-State NMR of Silicates and Zeolites", Wiley, Good book for specialists. M€ uller-Warmuth and coworkers were able to extend Bray's NMR approach to silicate (OH)−Al, in zeolites since the s.

is eliminated from high-resolution solid-state NMR by virtue of. High-Resolution Solid-State NMR of Silicates and Zeolites, G.

Engelhardt and D. Michel, Wiley, Chichester (). Transient techniques in NMR of solids: an introduction to theory and practice, Bernard C. Gerstein and C.

Dybowski, Academic Press, Orlando (). Nuclear Magnetic Resonance of Liquid Crystals, J. Emsley (Ed.), NATO ASI Series C. --Applied Spectroscopy This well-organized and up-to-date text gives a thorough account of the wide range of applications of multinuclear high-resolution solid-state NMR spectroscopy in silicate and zeolite science, with emphasis on the kinds of chemical information retrievable from NMR experiments.

(0 ) pp. Solid State NMR Spectroscopy and Refinery Catalysts Mohammad A. Khadim∗ and Mansour A. Al-Shafei P. Research & Development Center Saudi Aramco, Dhahran,Saudi Arabia ABSTRACT During the last two decades, high-resolution solid-state NMR spectroscopy has emerged as a powerful tool for the investigation of zeolitic structures.

Probing tin sites and Sn–OH groups. A Sn-β zeolite containing wt.% of Sn was prepared by the direct hydrothermal method 2,37 (denoted as Sn-β).

In order to enhance NMR. High-resolution silicon magic-angle sample-spinning NMR spectroscopic studies of a wide range of natural and synthetic silicates indicate (l) considerable overlap among the ranges of isotropic chemical shifts for crystals of different polymer types.

This expands upon the work of Lippmaa et a/. (), who found well-separated ranges; (2) a. a) Small- and wide-angle powder XRD patterns, b) solid-state 29Si CP-MAS NMR spectra, and c) representative TEM images [14] of the products obtained after 1, 7,10, and 12 days during hydrothermal synthesis (C) of mesostructured zeolite MFI nanosheets.

High resolution solid state 29 Si-NMR has recently been used to examine silicates, and synthetic and natural zeolites 1– has been possible through the use of dipolar decoupling, magicangle.

About this Item: John Wiley & Sons Inc, United States, Hardback. Condition: New. Language: English. Brand new Book. High-Resolution Solid-State NMR of Silicates and Zeolites Gunter Engelhardt and Dieter Michel "I strongly recommend this book as an important reference for scientists concerned with the structural properties of siliceous materials.".

several zeolites, but individual sites could not be resolved. High-resolution 17O NMR spectra of condensed silicates5,6 have been obtained by techniques such as double rotation (DOR)3 and dynamic angle spinning (DAS).3 Assignments of 17O spectra have been made by using correla-tions between Cq and Ł and the Si-O-Si bond angle.4,6 These.

NMR.I2-l6 High-resolution spectra can be obtained in this way,I7 often yielding quantitative structural information.

High-resolution oxygen- 17 N MR studies of silicates, however, are much more difficult as a result of quadrupolar couplings of the oxygen- 17 nuclei. Oxygen has a nuclear spin I. JORGEN SKIBSTED, High-resolution solid-state nuclear magnetic resonance spectroscopy of portland cement-based systems, A Practical Guide to Microstructural Analysis of Cementitious Materials, /b, (), ().

Engelhardt G. & Michel D. High-Resolution Solid-State NMR of Silicates and Zeolites John Wiley & Sons (). Bellmann F., Damidot D., Möser B. & Skibsted J. Improved evidence for the existence of an intermediate phase during hydration of tricalcium silicate. Cement Concrete Res. 40, – ().

Description High-resolution solid-state NMR of silicates and zeolites FB2

Rawal A. et al.Recent Advances in Solid-State NMR of Zeolites Recent Advances in Solid-State NMR of Zeolites Klinowski, J Zeolites have found widespread application as catalysts in a variety of important reactions, as sorbents and ion exchangers. While single crystals of natural minerals readily lend themselves to conventional methods of structural investigation, synthetic zeolites until.